when is libido the highest?!

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You're usually the most randy right during and right after your period (bad timing for the during). The during bit is due to a surge in hormones. The after bit is due to the fact that you'll soon be ovulating and you're most fertile.
Foods, exercise levels, medications, self esteem, stress, and many other things can affect your libido. Certain birth controls, depo provera for example, can lower the libido.
Yoga and pilates can actually enhance it, and you'll also feel sexier as your body starts to tone up.
A woman's libido usually surges between 30-40, whereas a mans will surge in his late teens and early twenties. This also has to do with fertility.